Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid  N -methylamides

A. A. Nikolin; A. A. Korlyukov; E. P. Kramarova; D. E. Arkhipov; A. G. Shipov; Yu. I. Baukov; Vad. V. Negrebetsky

doi:10.1007/s11172-018-2215-3

Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid N-methylamides

Authors: Nikolin A.A.¹, Korlyukov A.A.¹^,2, Kramarova E.P.¹, Arkhipov D.E.¹^,2, Shipov A.G.¹, Baukov Y.I.¹, Negrebetsky V.V.¹
Affiliations:
1. N. I. Pirogov Russian National Research Medical University
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Issue: Vol 67, No 7 (2018)
Pages: 1299-1306
Section: Article
URL: https://journals.rcsi.science/1066-5285/article/view/242740
DOI: https://doi.org/10.1007/s11172-018-2215-3
ID: 242740

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Abstract

Pentacoordinated monofluorosilanes R¹SO₂NHCHR₂C(O)N(Me)CH₂SiMe₂F containing moieties of N′-methyl-N-(organosulfonyl)-2-amino acid amides of glycine, alanine, and leucine as C,O-chelating ligands were synthesized via the reaction of corresponding disiloxanes with BF₃•Et₂O. The structures of obtained compounds were investigated by single-crystal X-ray diffraction analysis.