Classification and synthesis of nickel pincer complexes
- Authors: Gafurov Z.N.1,2, Kagilev A.A.2, Kantyukov A.O.2, Balabaev A.A.2, Sinyashin O.G.1, Yakhvarov D.G.1,2
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Affiliations:
- A. E. Arbuzov Institute of Organic and PhysicalChemistry, Russian Academy of Sciences
- Kazan Federal University
- Issue: Vol 67, No 3 (2018)
- Pages: 385-394
- Section: Reviews
- URL: https://journals.rcsi.science/1066-5285/article/view/242272
- DOI: https://doi.org/10.1007/s11172-018-2086-7
- ID: 242272
Cite item
Abstract
Over the past decades, the pincer ligands have attracted an increasing interest due to the unique properties of the coordination compounds they form. These monoanionic tridentate ligands are of great importance in organometallic and coordination chemistry. Their complexes with transition metals are used as homogeneous catalysts for various processes and also as functional materials with specified properties. The metal complexes formed by the pincer ligands provide an efficient alternative to the existing catalysts based on noble metals and, hence, the use of these complexes is a promising task of the modern chemical science. Therefore, nickel as the most accessible and inexpensive analog of palladium and platinum is of great practical interest. In this review, we consider the diversity of nickel complexes with pincer ligands, as well as the existing methods for their preparation and practical application.
About the authors
Z. N. Gafurov
A. E. Arbuzov Institute of Organic and PhysicalChemistry, Russian Academy of Sciences; Kazan Federal University
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008
A. A. Kagilev
Kazan Federal University
Email: yakhvar@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
A. O. Kantyukov
Kazan Federal University
Email: yakhvar@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
A. A. Balabaev
Kazan Federal University
Email: yakhvar@iopc.ru
Russian Federation, 18 ul. Kremlevskaya, Kazan, 420008
O. G. Sinyashin
A. E. Arbuzov Institute of Organic and PhysicalChemistry, Russian Academy of Sciences
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088
D. G. Yakhvarov
A. E. Arbuzov Institute of Organic and PhysicalChemistry, Russian Academy of Sciences; Kazan Federal University
Author for correspondence.
Email: yakhvar@iopc.ru
Russian Federation, 8 ul. Arbuzova, Kazan, 420088; 18 ul. Kremlevskaya, Kazan, 420008