Email this article Coordination polymers with adjustable dimensionality based on CuII and bis-imidazolyl bridging ligand
- Authors: Barsukova M.O.1, Samsonenko D.G.1,2, Goncharova T.V.3, Potapov A.S.3,4, Sapchenko S.A.1,2, Dybtsev D.N.1,2, Fedin V.P.1,2
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Affiliations:
- A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
- Department of Natural Sciences, Novosibirsk State University
- I. I. Polzunov Altai State Technical University
- National Research Tomsk Polytechnic University
- Issue: Vol 65, No 12 (2016)
- Pages: 2914-2919
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/239620
- DOI: https://doi.org/10.1007/s11172-016-1677-4
- ID: 239620
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Abstract
1,4-Bis(imidazol-1-yl)butane was synthesized from imidazole and 1,4-dibromobutane in an alkaline medium. A variation of the molar ratio of reagents in the system copper(II) chloride dihydrate and 1,4-bis(imidazol-1-yl)butane (bImB) upon heating in N,N-dimethylformamide resulted in the synthesis of two new coordination polymers [Cu(bImB)Cl2] (1) and [Cu(bImB)2Cl2] (2), which were structurally characterized. Product 1 was found to possess a chain structure, while structure 2 is built of neutral layers, with the dimensionality of the extended coordination structures being determined by the reaction conditions. The new compounds were characterized by IR spectroscopy, elemental analysis, and powder X-ray diffraction data.
About the authors
M. O. Barsukova
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090
D. G. Samsonenko
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Department of Natural Sciences, Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
T. V. Goncharova
I. I. Polzunov Altai State Technical University
Email: cluster@niic.nsc.ru
Russian Federation, 46 prosp. Lenina, Barnaul, 656038
A. S. Potapov
I. I. Polzunov Altai State Technical University; National Research Tomsk Polytechnic University
Email: cluster@niic.nsc.ru
Russian Federation, 46 prosp. Lenina, Barnaul, 656038; 30 prosp. Lenina, Tomsk, 634050
S. A. Sapchenko
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Department of Natural Sciences, Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
D. N. Dybtsev
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Department of Natural Sciences, Novosibirsk State University
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
V. P. Fedin
A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences; Department of Natural Sciences, Novosibirsk State University
Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent’eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090
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