Structure of ionic cluster complex [{Er(H 2 O) 2 (phen) 2 (μ-OH)} 2 ][Re 4 Te 4 (CN) 12 ]•13H 2 O

Yu. M. Litvinova; Ya. M. Gayfulin; D. G. Samsonenko; Yu. V. Mironov

doi:10.1007/s11172-016-1588-4

Structure of ionic cluster complex [{Er(H₂O)₂(phen)₂(μ-OH)}₂][Re₄Te₄(CN)₁₂]•13H₂O

Authors: Litvinova Y.M.¹, Gayfulin Y.M.¹, Samsonenko D.G.¹^,2, Mironov Y.V.¹^,2
Affiliations:
1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
2. Novosibirsk State University
Issue: Vol 65, No 10 (2016)
Pages: 2355-2357
Section: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/239046
DOI: https://doi.org/10.1007/s11172-016-1588-4
ID: 239046

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Abstract
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Abstract

The rhenium cluster complex [{Er(H₂O)₂(phen)₂(μ-OH)}₂][Re₄Te₄(CN)₁₂]•13H₂O (1) was synthesized and structurally characterized. The structure of the salt was determined by single-crystal X-ray diffraction analysis. Compound 1 contains a new dimeric cationic fragment [{Er(H₂O)₂(phen)₂(μ-OH)}]₂⁴⁺.

Keywords

rhenium, tetrahedral cluster complex, lanthanide complexes, crystal structure

About the authors

Yu. M. Litvinova

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: yuri@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent´eva, Novosibirsk, 630090

Ya. M. Gayfulin

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: yuri@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent´eva, Novosibirsk, 630090

D. G. Samsonenko

A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: yuri@niic.nsc.ru
Russian Federation, 3 prosp. Akad. Lavrent´eva, Novosibirsk, 630090; 2 ul. Pirogova, Novosibirsk, 630090

Yu. V. Mironov