Email this article Anodic dissolution of tin in alcohols
- Authors: Vereshchagin A.N.1, Elinson M.N.1, Goloveshkin A.S.2, Novikov R.A.1, Egorov M.P.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 65, No 3 (2016)
- Pages: 840-843
- Section: Brief Communications
- URL: https://journals.rcsi.science/1066-5285/article/view/237733
- DOI: https://doi.org/10.1007/s11172-016-1387-y
- ID: 237733
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Abstract
Tin(II) alcoholates Sn(OR)2 are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxyhydroxide Sn3O2(OН)2 used as an anode or its composite component in lithium cells.
About the authors
A. N. Vereshchagin
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: vereshchagin@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
M. N. Elinson
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vereshchagin@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. S. Goloveshkin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: vereshchagin@ioc.ac.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
R. A. Novikov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vereshchagin@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
M. P. Egorov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: vereshchagin@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
