Email this article Electrochemical synthesis of nanocomposite of palladium nanoparticles with polymer viologen-containing nanocapsule
- Authors: Yanilkin V.V.1, Nastapova N.V.1, Sultanova E.D.1, Nasretdinova G.R.1, Mukhitova R.K.1, Ziganshina A.Y.1, Nizameev I.R.1, Kadirov M.K.1
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Affiliations:
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
- Issue: Vol 65, No 1 (2016)
- Pages: 125-132
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/236845
- DOI: https://doi.org/10.1007/s11172-016-1274-6
- ID: 236845
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Abstract
An efficient mediated electrosynthesis of the spherical (85 nm) nanocomposite material Pd@p(MVCA8+-co-St) was carried out in an aqueous medium. Ultrasmall palladium nanoparticles (3—8 nm) are stabilized in nanocapsules of water-soluble nanoparticles of the copolymer p(MVCA8+-co-St) consisting of tetraviologen calix[4]resorcinol (MVCA8+) with styrene (St). The role of the mediator is played by viologen units of a polymer nanoparticle at potentials of the MV2+/MV∙+ redox couple. The high catalytic activity of the nanocomposite material in the reduction of nitrophenol with sodium borohydride is shown.
About the authors
V. V. Yanilkin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Author for correspondence.
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
N. V. Nastapova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
E. D. Sultanova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
G. R. Nasretdinova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
R. K. Mukhitova
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
A. Yu. Ziganshina
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
I. R. Nizameev
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
M. K. Kadirov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences
Email: yanilkin@iopc.ru
Russian Federation, 8 ul. Akad. Arbuzova, Kazan, 420088
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