Reactions of UF6 and HF with Ethanol
- 作者: Gromov O.1, Khorozova O.2, Travin S.3, Atakhanova E.2
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隶属关系:
- Bochvar High-Tech Research Institute of Inorganic Materials
- Leading Research Institute of Chemical Technology
- Semenov Institute of Chemical Physics
- 期: 卷 60, 编号 2 (2018)
- 页面: 152-157
- 栏目: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/224406
- DOI: https://doi.org/10.1134/S1066362218020042
- ID: 224406
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详细
Qualitative studies were performed, and the feasibility of ethanol fluorination by its reactions with anhydrous HF and UF6 was demonstrated. The reaction occurs at temperatures of up to 150°С via replacement of OH groups with probable formation of Freon 161 and substitution of СH groups with the most probable formation of Freon 152. The Freons were identified by IR spectroscopy. The solid reaction products mainly consist of intermediate uranium fluorides. The formation of uranyl fluoride is not proved unambiguously.
作者简介
O. Gromov
Bochvar High-Tech Research Institute of Inorganic Materials
编辑信件的主要联系方式.
Email: ollgromov@mail.ru
俄罗斯联邦, Moscow, 123060
O. Khorozova
Leading Research Institute of Chemical Technology
Email: ollgromov@mail.ru
俄罗斯联邦, Kashirskoe sh. 33, Moscow, 115409
S. Travin
Semenov Institute of Chemical Physics
Email: ollgromov@mail.ru
俄罗斯联邦, ul. Kosygina 4, Moscow, 119991
E. Atakhanova
Leading Research Institute of Chemical Technology
Email: ollgromov@mail.ru
俄罗斯联邦, Kashirskoe sh. 33, Moscow, 115409