Reactions of UF6 and HF with Ethanol


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Qualitative studies were performed, and the feasibility of ethanol fluorination by its reactions with anhydrous HF and UF6 was demonstrated. The reaction occurs at temperatures of up to 150°С via replacement of OH groups with probable formation of Freon 161 and substitution of СH groups with the most probable formation of Freon 152. The Freons were identified by IR spectroscopy. The solid reaction products mainly consist of intermediate uranium fluorides. The formation of uranyl fluoride is not proved unambiguously.

作者简介

O. Gromov

Bochvar High-Tech Research Institute of Inorganic Materials

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Email: ollgromov@mail.ru
俄罗斯联邦, Moscow, 123060

O. Khorozova

Leading Research Institute of Chemical Technology

Email: ollgromov@mail.ru
俄罗斯联邦, Kashirskoe sh. 33, Moscow, 115409

S. Travin

Semenov Institute of Chemical Physics

Email: ollgromov@mail.ru
俄罗斯联邦, ul. Kosygina 4, Moscow, 119991

E. Atakhanova

Leading Research Institute of Chemical Technology

Email: ollgromov@mail.ru
俄罗斯联邦, Kashirskoe sh. 33, Moscow, 115409


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