Effect of Irradiation on the Lower Temperature Limit of Flame Propagation in the TODGA-Based Extraction Mixture


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Abstract

The effect of accelerated electrons on the lower temperature limit of flame propagation in mixtures containing N, N, N′,N′-tetra-n-octyldiglycolamide and n-alcohol (n-decanol and n-nonanol) in various concentrations in Isopar-M was studied. In the extraction mixtures irradiated to a dose of 0.5 MGy, the lower temperature limit of the flame propagation (TL) decreases insignificantly: by 2–3°C for the mixtures with 20% n-alcohol and by 6–11°C for those with 6% n-alcohol. The TL values for the extraction mixtures, including irradiated mixtures, are no lower than 64°C.

About the authors

I. V. Skvortsov

Frumkin Institute of Physical Chemistry and Electrochemistry; Scientific and Technical Center for Nuclear and Radiation Safety

Email: bl174@bk.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071; ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140

E. V. Belova

Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: bl174@bk.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

A. V. Rodin

Frumkin Institute of Physical Chemistry and Electrochemistry; Scientific and Technical Center for Nuclear and Radiation Safety

Email: bl174@bk.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071; ul. Malaya Krasnosel’skaya 2/8, korp. 5, Moscow, 107140

B. F. Myasoedov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bl174@bk.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071

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