Numerical Modeling of Leaching of Aluminophosphate Glass in the Batch Mode in the Presence of Bentonite
- Authors: Boldyrev K.A.1, Martynov K.V.2, Kryuchkov D.V.1, Zakharova E.V.2, Ermolaev V.M.2
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Affiliations:
- Nuclear Safety Institute
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 61, No 5 (2019)
- Pages: 612-618
- Section: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/225347
- DOI: https://doi.org/10.1134/S1066362219050151
- ID: 225347
Cite item
Abstract
A numerical kinetic model of leaching of aluminophosphate glass, an analog of a glass matrix for radioactive waste, in the batch mode in the presence of bentonite, taking into account the sorption processes, was constructed on the basis of the experimental data. The model describes the glass dissolution kinetics within the framework of the concept of approach to the equilibrium, taking into account shielding of the surface with glass corrosion products. The sorption is described within the framework of the ion exchange model. Modeling was performed using PhreeqC code.
About the authors
K. A. Boldyrev
Nuclear Safety Institute
Author for correspondence.
Email: kaboldyrev@gmail.com
Russian Federation, Bol’shaya Tul’skaya ul. 52, Moscow, 115191
K. V. Martynov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kaboldyrev@gmail.com
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
D. V. Kryuchkov
Nuclear Safety Institute
Email: kaboldyrev@gmail.com
Russian Federation, Bol’shaya Tul’skaya ul. 52, Moscow, 115191
E. V. Zakharova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kaboldyrev@gmail.com
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
V. M. Ermolaev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kaboldyrev@gmail.com
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071