Absorption of nitrogen hemioxide in aqueous solutions of gas treatment systems upon dissolution of UN in nitric acid
- Authors: Kulyukhin S.A.1, Bessonov A.A.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 59, No 3 (2017)
- Pages: 280-283
- Section: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/223929
- DOI: https://doi.org/10.1134/S1066362217030109
- ID: 223929
Cite item
Abstract
The absorption of N2O from an air flow in various aqueous solutions at 293–298 K was studied. The maximal N2O absorption under the experimental conditions is reached for water (~22–24%) and saturated solution of K2Cr2O7 in concentrated H2SO4 in the presence of Al2O3 and without it (~34 and ~30%, respectively). In concentrated HNO3 and NH4OH solutions and in 1.0 M NaOH and N2H4·nH2O solutions, the degree of the N2O absorption varied from ~7.5 to ~11.5%. Similar degree of absorption was obtained with 0.5 M (NH2)2CO (~11%). In the other solutions tested, the degree of the N2O absorption did not exceed ~4.0%.
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About the authors
S. A. Kulyukhin
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
A. A. Bessonov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071