Email this article Crystal structure of [Co(en)3][NpO4(OH)2]·5H2O (en = ethylenediamine, H2N(CH2)2NH2)
- Authors: Charushnikova I.A.1, Krot N.N.1, Grigor’ev M.S.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 59, No 3 (2017)
- Pages: 219-224
- Section: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/223882
- DOI: https://doi.org/10.1134/S1066362217030018
- ID: 223882
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Abstract
A Np(VII) compound with [Co(en)3]3+ cations, [Co(en)3][NpO4(OH)2]·5H2O (en = ethylenediamine), was synthesized and studied by single crystal X-ray diffraction. The structure consists of [NpO4(OH)2]3– anions and [Co(en)3]3+ cations forming electrically neutral layers, between which water molecules are arranged. A three-dimensional network of hydrogen bonds involving all the constituents of the structure is formed in the crystal. The effect of hydrogen bonding on the geometric characteristics of [NpO4(OH)2]3– anions is discussed.
About the authors
I. A. Charushnikova
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
N. N. Krot
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
M. S. Grigor’ev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: charushnikovai@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
