Gas-phase conversion of the U, Sr, Mo, and Zr oxides into water-soluble compounds in the NOx–H2O (vapor)–air atmosphere
- Authors: Kulyukhin S.A.1, Nevolin Y.M.1, Mizina L.V.1, Konovalova N.A.1, Gordeev A.V.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 58, No 1 (2016)
- Pages: 13-29
- Section: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/223328
- DOI: https://doi.org/10.1134/S1066362216010045
- ID: 223328
Cite item
Abstract
The gas-phase conversion of U3O8, MoO3, SrO, and their mechanical mixtures, and also of ZrO2 into water-soluble compounds in the NOx–H2O (vapor)–air atmosphere was studied. In the course of gas-phase conversion, U3O8 and SrO transform into water-soluble compounds (nitrates, hydroxonitrates), whereas MoO3 and ZrO2 undergo no changes. The principal possibility of separating U from Mo and Zr by gas-phase conversion of the oxides in the NOx–H2O (vapor)–air atmosphere was demonstrated.
Keywords
About the authors
S. A. Kulyukhin
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
Yu. M. Nevolin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
L. V. Mizina
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
N. A. Konovalova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071
A. V. Gordeev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: kulyukhin@ipc.rssi.ru
Russian Federation, Leninskii pr. 31, korp. 4, Moscow, 119071