Synthesis and crystal structure of Ag2[(UO2)6(MoO4)7(H2O)2](H2O)2
- Authors: Nazarchuk E.V.1, Siidra O.I.1, Krivovichev S.V.1
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Affiliations:
- St. Petersburg State University
- Issue: Vol 58, No 1 (2016)
- Pages: 1-5
- Section: Article
- URL: https://journals.rcsi.science/1066-3622/article/view/223325
- DOI: https://doi.org/10.1134/S106636221601001X
- ID: 223325
Cite item
Abstract
The compound Ag2[(UO2)6(MoO4)7(H2O)2](H2O)2 was prepared at 220°С in the course of hydrothermal synthesis. The phase crystallizes in the rhombic system, space group Pbcm, а = 14.1309(9), b = 10.6595(7), c = 25.8281(16) Å, V = 3890.44 Å3. The crystal structure was solved by direct methods and refined to R1 = 0.049 for 4394 reflections with Fo > 4σ(Fo) and 0.1025 for all the 8239 reflections. The structure is based on a framework constituted by UO7 and MoO4 polyhedra sharing common vertices. In the framework, there are two systems of channels occupied by Ag+ cations and water molecules and oriented along [001] and [010].
About the authors
E. V. Nazarchuk
St. Petersburg State University
Author for correspondence.
Email: e_nazarchuk@mail.ru
Russian Federation, Universitetskaya nab. 7/9, St. Petersburg, 199034
O. I. Siidra
St. Petersburg State University
Email: e_nazarchuk@mail.ru
Russian Federation, Universitetskaya nab. 7/9, St. Petersburg, 199034
S. V. Krivovichev
St. Petersburg State University
Email: e_nazarchuk@mail.ru
Russian Federation, Universitetskaya nab. 7/9, St. Petersburg, 199034