Thermal Oxidation of a Carbon Condensate Formed in High-Frequency Carbon and Carbon–Nickel Plasma Flow


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We have reported on the comparative characteristics of thermal oxidation of a carbon condensate prepared by high-frequency arc evaporation of graphite rods and a rod with a hollow center filled with nickel powder. In the latter case, along with different forms of nanodisperse carbon, nickel particles with nickel core–carbon shell structures are formed. It has been found that the processes of the thermal oxidation of carbon condensates with and without nickel differ significantly. Nickel particles with the carbon shell exhibit catalytic properties with respect to the oxidation of nanosized carbon structures. A noticeable difference between the temperatures of the end of the oxidation process for various carbon nanoparticles and nickel particles with the carbon shell has been established. The study is aimed at investigations of the effect of nickel nanoparticles on the dynamics of carbon condensate oxidation upon heating in the argon–oxygen flow.

作者简介

G. Churilov

Kirensky Institute of Physics, Siberian Branch; Siberian Federal University

编辑信件的主要联系方式.
Email: churilov@iph.krasn.ru
俄罗斯联邦, Krasnoyarsk, 660036; Krasnoyarsk, 660041

N. Nikolaev

Kirensky Institute of Physics, Siberian Branch; Siberian Federal University

Email: churilov@iph.krasn.ru
俄罗斯联邦, Krasnoyarsk, 660036; Krasnoyarsk, 660041

A. Cherepakhin

Siberian Federal University

Email: churilov@iph.krasn.ru
俄罗斯联邦, Krasnoyarsk, 660041

A. Dudnik

Kirensky Institute of Physics, Siberian Branch; Siberian Federal University

Email: churilov@iph.krasn.ru
俄罗斯联邦, Krasnoyarsk, 660036; Krasnoyarsk, 660041

E. Tomashevich

Institute of Chemistry and Chemical Technology, Siberian Branch

Email: churilov@iph.krasn.ru
俄罗斯联邦, Krasnoyarsk, 660036

M. Trenikhin

Institute for Problems of Hydrocarbon Processing, Siberian Branch

Email: churilov@iph.krasn.ru
俄罗斯联邦, Omsk, 644040

N. Bulina

Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch

Email: churilov@iph.krasn.ru
俄罗斯联邦, Novosibirsk, 630128


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