Interdiffusion of Mo and W in the Shells of Electrogenerating Channels under Reactor Irradiation

Resumo

Abstract—A detailed analysis of interdiffusion processes in emitter shells of electrogenerating channels (EGC) of reactors for space application after long term reactor irradiation is performed. Interdiffusion of Mo and W in the mono- and polycrystalline manufacturing technology with the W layer applied over them with thickness on the order of 10^–4 m with irradiation time from 3000 to 12 350 h and at temperatures from 1350 to 1670°C is studied. One of the mechanisms which facilitate the pore-formation process in the W layer and its separation is demonstrated. A method of calculating the activation energy, temperature, and residual thickness of the W layer on the basis of which the state of the shells can be estimated for a long time from the start of irradiation is proposed.