Study of the Characteristics of Elementary Processes in a Chain Hydrogen Burning Reaction in Oxygen


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Abstract

The characteristics of possible chain explosive hydrogen burning reactions in an oxidizing medium are calculated on the potential energy surface. Specifically, reactions H2 + O2 → H2O + O, H2 + O2 → HO2 + H, and H2 + O2 → OH + OH are considered. Special attention is devoted to the production of a pair of fast highly reactive OH radicals. Because of the high activation threshold, this reaction is often excluded from the known kinetic scheme of hydrogen burning. However, a spread in estimates of kinetic characteristics and a disagreement between theoretical predictions with experimental results suggest that the kinetic scheme should be refined.

About the authors

M. E. Bychkov

Troitsk Institute of Innovation and Thermonuclear Research

Author for correspondence.
Email: bychkov.m.e@gmail.com
Russian Federation, Troitsk, Moscow, 142190

Yu. V. Petrushevich

Troitsk Institute of Innovation and Thermonuclear Research

Email: bychkov.m.e@gmail.com
Russian Federation, Troitsk, Moscow, 142190

A. N. Starostin

Troitsk Institute of Innovation and Thermonuclear Research

Email: bychkov.m.e@gmail.com
Russian Federation, Troitsk, Moscow, 142190

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