Electron paramagnetic resonance of Cr3+ ions in ABO3 (A = Sc, Lu, In) diamagnetic crystals


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A magnetic resonance method is applied to the investigation of a number of isostructural diamagnetic compounds ABO3 (A = Sc, Lu, In) with small additions of Cr3+ ions (S = 3/2) sufficient to observe single-ion spectra. It is shown that the resonance spectra for isolated Cr3+ ions can be described to a good accuracy by the ordinary axial spin Hamiltonian for 3d ions in octahedral oxygen environment. The parameters of the spin Hamiltonian are determined. It is established that Cr3+ ions in these crystals are characterized by easy-axis-type anisotropy.

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A. Vorotynov

Kirenskii Institute of Physics, Siberian Branch

编辑信件的主要联系方式.
Email: sasa@iph.krasn.ru
俄罗斯联邦, Akademgorodok, Krasnoyarsk, 660036

S. Ovchinnikov

Kirenskii Institute of Physics, Siberian Branch

Email: sasa@iph.krasn.ru
俄罗斯联邦, Akademgorodok, Krasnoyarsk, 660036

V. Rudenko

Kirenskii Institute of Physics, Siberian Branch

Email: sasa@iph.krasn.ru
俄罗斯联邦, Akademgorodok, Krasnoyarsk, 660036

O. Vorotynova

Siberian Federal University

Email: sasa@iph.krasn.ru
俄罗斯联邦, Krasnoyarsk, 660041

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