Crystallographic Approach to the [2 + 2] Photocycloaddition Topochemical Reactions of Unsaturated Compounds with Single Crystal Retention
- 作者: Kuz’mina L.1, Vedernikov A.1,2, Gromov S.1,2, Alfimov M.1,2
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Photochemistry Center, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences
- 期: 卷 64, 编号 5 (2019)
- 页面: 691-712
- 栏目: Reviews
- URL: https://journals.rcsi.science/1063-7745/article/view/194174
- DOI: https://doi.org/10.1134/S1063774519050122
- ID: 194174
如何引用文章
详细
Based on the results of authors' studies, an approach to the analysis of [2 + 2] photocycloaddition (PCA) topochemical reactions of unsaturated compounds, occurring in a single crystal with either its retention or decomposition under exposure to visible light, has been developed. The main crystal packings, favorable for photoreaction in crystal, are revealed. Conditions for PCA reaction with single crystal retention are established. The factors increasing the probability of implementing crystal packing motifs that are favorable for this reaction (by chemical modification of structural units) are analyzed. The fact of extraordinary implementation of both direct and back (under UV irradiation) photoreactions in the same single crystal is explained.
作者简介
L. Kuz’mina
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: kuzmina@igic.ras.ru
俄罗斯联邦, Moscow, 119991
A. Vedernikov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Photochemistry Center, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences
Email: kuzmina@igic.ras.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119421
S. Gromov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Photochemistry Center, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences
Email: kuzmina@igic.ras.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119421
M. Alfimov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Photochemistry Center, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences
Email: kuzmina@igic.ras.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119421