Enviar artigo por via de e-mail The First Seven-Coordinated Triiodo Complex of Rhenium(III)
- Autores: Schoultz X.1, Gerber T.I.1, Betz R.1, Hosten E.C.1
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Afiliações:
- Department of Chemistry
- Edição: Volume 62, Nº 7 (2017)
- Páginas: 1135-1137
- Seção: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/191903
- DOI: https://doi.org/10.1134/S1063774517070239
- ID: 191903
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Resumo
The reaction of cis-[ReO2I(PPh3)2] with tert-butyl isocyanide in benzene led to the isolation of the complex [ReI3(CN-t-Bu)3(PPh3)] (1). The complex is unusual since it contains bulky ligands with large cone angles, i.e. three iodides, three isocyanides with tert-butyl groups and a triphenylphosphine as ligands in a seven-coordinate geometry around the rhenium(III) metal ion.
Sobre autores
X. Schoultz
Department of Chemistry
Email: thomas.gerber@nmmu.ac.za
República da África do Sul, Port Elizabeth
T. Gerber
Department of Chemistry
Autor responsável pela correspondência
Email: thomas.gerber@nmmu.ac.za
República da África do Sul, Port Elizabeth
R. Betz
Department of Chemistry
Email: thomas.gerber@nmmu.ac.za
República da África do Sul, Port Elizabeth
E. Hosten
Department of Chemistry
Email: thomas.gerber@nmmu.ac.za
República da África do Sul, Port Elizabeth
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