Anomalies of properties in a series of K2CoxNi1−x(SO4)2 · 6H2O mixed crystals


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The microhardness and thermal stability of K2CoxNi1x(SO4)2 · 6H2O mixed crystals have been investigated. Microhardness peaks and dehydration onset temperatures are found in the composition range x = 0.05–0.23. The observed anomalies of properties are related to the anomalous changes in the structural parameters of the crystals in this composition range with an increase in the cobalt content. It is shown that structural imperfection of the crystals depends on the sectorial inhomogeneity and reaches a maximum at x = 0.43–0.54.

作者简介

E. Rudneva

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

V. Manomenova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

M. Koldaeva

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

N. Sorokina

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

A. Voloshin

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

编辑信件的主要联系方式.
Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

V. Grebenev

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

I. Verin

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

M. Lyasnikova

Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,”

Email: labsol@crys.ras.ru
俄罗斯联邦, Moscow, 119333

V. Masalov

Institute of Solid State Physics

Email: labsol@crys.ras.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

A. Zhokhov

Institute of Solid State Physics

Email: labsol@crys.ras.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

G. Emelchenko

Institute of Solid State Physics

Email: labsol@crys.ras.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

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