Crystal Structure and Molecular Conformational Studies of Allyl 6-Amino-5-cyano-4-(4-fluorophenyl)-2-methyl-4H-pyran-3-carboxylate
- Authors: Mohandas T.1, Kumar C.U.2, Krishnan G.A.3, Pillai M.V.2, Sakthivel P.4
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Affiliations:
- Department of Physics, K. Ramakrishnan College of Engineering, Samayapuram
- Department of Chemistry, School of Advanced Sciences, Kalasalingam Academy of Research and Education (Deemed to be University)
- Department of Physics, Saranathan College of Engineering, Panjapur
- Department of Physics, Urumu Dhanalakshmi College
- Issue: Vol 64, No 7 (2019)
- Pages: 1103-1107
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194485
- DOI: https://doi.org/10.1134/S1063774519070101
- ID: 194485
Cite item
Abstract
The allyl 6-amino-5-cyano-4-(4-fluorophenyl)-2-methyl-4H-pyran-3-carboxylate, C17H15FN2O3, compound adopts a triclinic crystal system with the sp. gr. \(P\bar {1}\), Z = 2. The 4H-pyran ring adopts a boat conformation with their respective parameters (Q = 0.2384(26) Å, θ = 99.46(65)°, Φ = 10.3(7)°). The fluorophenyl ring is essentially planar. The dihedral angle between fluorophenyl and pyran rings is found to be 85.81(15)°. The structure is stabilized by intermolecular interaction. The N–H···N and N–H···O interactions form a graph set motifs of R\(_{2}^{2}\) (12) and R\(_{4}^{2}\) (20), respectively.
About the authors
T. Mohandas
Department of Physics, K. Ramakrishnan College of Engineering, Samayapuram
Email: sakthi2udc@gmail.com
India, Trichy, Tamil Nadu, 621112
C. Udhaya Kumar
Department of Chemistry, School of Advanced Sciences,Kalasalingam Academy of Research and Education (Deemed to be University)
Email: sakthi2udc@gmail.com
India, Krishnankoil, Tamil Nadu, 626126
G. Anantha Krishnan
Department of Physics, Saranathan College of Engineering, Panjapur
Email: sakthi2udc@gmail.com
India, Trichy, Tamil Nadu, 620012
M. Velayutham Pillai
Department of Chemistry, School of Advanced Sciences,Kalasalingam Academy of Research and Education (Deemed to be University)
Author for correspondence.
Email: m.velayuthampillai@klu.ac.in
India, Krishnankoil, Tamil Nadu, 626126
P. Sakthivel
Department of Physics, Urumu Dhanalakshmi College
Author for correspondence.
Email: sakthi2udc@gmail.com
India, Trichy, Tamil Nadu, 620019