Synthesis and Crystal Structure of [Benzyl N'-[[2-(hydroxy-kO)phenyl]ethylene]-N-[[2-(hydroxy-kO)phenyl]methylene]-carbamohydrazonothioato-kN,kN']-ethanol-dioxido-uranium


如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The uranyl compound UO2(L')EtOH (L' = benzyl N-(2-(oxidanyl)benzylidene)-N'-((2-(1-oxidanyl)phenyl)ethylidene) carbamohydrazonothioate) was synthesized and its molecular and crystal structure was determined by X-ray diffraction. The compound crystallizes in the triclinic sp. gr. P\(\bar {1}\), Z = 2. The coordination geometry about the uranium atom is distorted pentagonal bipyramidal consisting of a UO2O4N2 polyhedron where the oxido ligands occupy axial positions with a symmetric linear structure (O=U=O angle = 179.11(12)°). The pentagonal plane (N2O3) is formed by the dinegative, tetradentate Schiff base ligand (N2O2) and the oxygen atom of the coordinated alcohol ligand. In the complex, the ligand adopts a propeller-like conformation.

作者简介

R. Takjoo

Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad

编辑信件的主要联系方式.
Email: r.takjoo@um.ac.ir
伊朗伊斯兰共和国, Mashhad

J. Mague

Department of Chemistry, Tulane University

编辑信件的主要联系方式.
Email: joelt@tulane.edu
美国, New Orleans, LA 70118

补充文件

附件文件
动作
1. JATS XML

版权所有 © Pleiades Publishing, Inc., 2019