Synthesis, Structure, and Luminescence of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and 4-Nitrophthalate Ligands
- Authors: Gao-Feng Wang 1, Shu-Wen Sun 1
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Affiliations:
- Department of Applied Chemistry, Yuncheng University
- Issue: Vol 64, No 7 (2019)
- Pages: 1075-1079
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194440
- DOI: https://doi.org/10.1134/S1063774519070265
- ID: 194440
Cite item
Abstract
A zinc coordination polymer with V-shaped ligands, [L1Zn(npa)]n (L1 = bis(4-(2'-methylimidazol)phenyl)sulfone, H2npa = 4-nitrophthalic acid) has been synthesized under solvothermal conditions. The structure has been determined by single-crystal X-ray diffraction analysis and characterized by IR spectra, and elemental analyses. In crystal adjacent [Zn2(npa)2] units linked by four bridging ligands L1 form 2D layers, which are entangled between each other giving inclined interpenetration with the angle of 52.9°, thus resulting in a complicated 3D unique network. Moreover, luminescent properties of the title compound have been investigated.
About the authors
Gao-Feng Wang
Department of Applied Chemistry, Yuncheng University
Author for correspondence.
Email: wgf1979@126.com
China, Yuncheng, 044000
Shu-Wen Sun
Department of Applied Chemistry, Yuncheng University
Email: wgf1979@126.com
China, Yuncheng, 044000