Synthesis, Structure, and Luminescence of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and 4-Nitrophthalate Ligands


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Аннотация

A zinc coordination polymer with V-shaped ligands, [L1Zn(npa)]n (L1 = bis(4-(2'-methylimidazol)phenyl)sulfone, H2npa = 4-nitrophthalic acid) has been synthesized under solvothermal conditions. The structure has been determined by single-crystal X-ray diffraction analysis and characterized by IR spectra, and elemental analyses. In crystal adjacent [Zn2(npa)2] units linked by four bridging ligands L1 form 2D layers, which are entangled between each other giving inclined interpenetration with the angle of 52.9°, thus resulting in a complicated 3D unique network. Moreover, luminescent properties of the title compound have been investigated.

Авторлар туралы

Gao-Feng Wang

Department of Applied Chemistry, Yuncheng University

Хат алмасуға жауапты Автор.
Email: wgf1979@126.com
ҚХР, Yuncheng, 044000

Shu-Wen Sun

Department of Applied Chemistry, Yuncheng University

Email: wgf1979@126.com
ҚХР, Yuncheng, 044000

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