Email this article Synthesis and Structural Characterization of Two Tetra-Coordinated Co(II) Complexes with Benzimidazole Derivatives
- Authors: Shu-Wen Sun 1, Gao-Feng Wang 1
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Affiliations:
- Department of Applied Chemistry, Yuncheng University
- Issue: Vol 64, No 7 (2019)
- Pages: 1066-1070
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194426
- DOI: https://doi.org/10.1134/S1063774519070216
- ID: 194426
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Abstract
Two mononuclear tetra-coordinated cobalt(II) complexes with molecular formula [Co(L)2(SCN)2] (L = 1-methylbenzimidazole (mbim), 1; L = 1-methyl-2-aminobenzimidazole (mabim), 2) were prepared and characterized by IR, EA, and single crystal X-ray diffraction. The central Co(II) ion is tetrahedrally coordinated by two nitrogen atoms of benzimidazole-based ligands and two nitrogen atoms of two thiocyanato ligands. In the crystal structure of 1 and 2, molecules are linked through intermolecular hydrogen bonds and π···π interactions forming a 3D network.
About the authors
Shu-Wen Sun
Department of Applied Chemistry, Yuncheng University
Email: wgf1979@126.com
China, Yuncheng, 044000
Gao-Feng Wang
Department of Applied Chemistry, Yuncheng University
Author for correspondence.
Email: wgf1979@126.com
China, Yuncheng, 044000
