Hydrothermal Synthesis and Physicochemical Characterization of Organic-Inorganic Isopolyoxomolybdate-Based Hybrid (C6N6)4[H4Mo8O26]
- Авторлар: Ftini M.1, Chaabani A.1, Boubaker T.1
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Мекемелер:
- Department of Chemistry, University of Monastir
- Шығарылым: Том 64, № 7 (2019)
- Беттер: 1023-1029
- Бөлім: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/194388
- DOI: https://doi.org/10.1134/S1063774519070058
- ID: 194388
Дәйексөз келтіру
Аннотация
A novel polyoxomolybdate-based organic-inorganic hybrid compound, (C6H6)4[H4Mo8O26], has been synthesized hydrothermally and characterized structurally by the elemental analysis, single crystal X-ray diffraction, thermogravimetric analysis, infrared and ultraviolet–visible spectroscopies, and cyclic voltammetry. Crystallographic data for the compound are: triclinic system, space group \(P\mathop 1\limits^\_ \), unit cell parameters a = 9.605(2) Å, b = 9.991(3) Å, c = 10.718(3) Å, α = 83.75(2)°, β = 76.45(3)°, γ = 69.07(3)°, Z = 1. The crystal consists of the clusters β-[Mo8O26]4– and four organic molecules C6H6. Isopolymolybdate anions are connected with the organic molecules via a complex hydrogen-bonded network, which generate a three-dimensional framework.
Авторлар туралы
M. Ftini
Department of Chemistry, University of Monastir
Хат алмасуға жауапты Автор.
Email: mohamedmongi@yahoo.fr
Тунис, Monastir
A. Chaabani
Department of Chemistry, University of Monastir
Email: mohamedmongi@yahoo.fr
Тунис, Monastir
T. Boubaker
Department of Chemistry, University of Monastir
Email: mohamedmongi@yahoo.fr
Тунис, Monastir