Email this article Synthesis and Structural Characterization of a Nickel Coordination Polymer Based on 4-(1H-Imidazol-1-yl)phenyl)methanone with Phthalic Acid
- Authors: Shu-Wen Sun 1, Wang G.1, Zhang X.2
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Affiliations:
- Department of Applied Chemistry, Yuncheng University
- MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology
- Issue: Vol 63, No 7 (2018)
- Pages: 1120-1123
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/193391
- DOI: https://doi.org/10.1134/S1063774518070246
- ID: 193391
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Abstract
A nickel coordination polymer with V-shaped ligands, {[(L1)2Ni(H2O)2] · 2(C8H5O4)}n, (L1 = 4-(1H-imidazol-1-yl)phenyl)methanone) has been synthesized under the solvothermal conditions. The structure has been determined by the single-crystal X-ray diffraction analysis and characterized by the infrared spectroscopy and elemental analysis. The crystal is crystallized in the monoclinic sp. gr. P21/c with the unit cell parameters a = 15.6387(3) Å, b = 8.0526(2) Å, c = 24.4791(6) Å, and β = 129.2350(10)°, Z = 2. The adjacent [Ni(H2O)2] units are linked by two bridging L1 ligands to form 1D looped chains, which are extended by the hydrogen bonds to yield a 3D framework.
About the authors
Shu-Wen Sun
Department of Applied Chemistry, Yuncheng University
Author for correspondence.
Email: sunsw0819@163.com
China, Yuncheng, 044000
Gao-Feng Wang
Department of Applied Chemistry, Yuncheng University
Email: sunsw0819@163.com
China, Yuncheng, 044000
Xiao Zhang
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage,School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Email: sunsw0819@163.com
China, Harbin, 150080
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