Synthesis and Structural Characterization of a Nickel Coordination Polymer Based on 4-(1H-Imidazol-1-yl)phenyl)methanone with Phthalic Acid


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Аннотация

A nickel coordination polymer with V-shaped ligands, {[(L1)2Ni(H2O)2] · 2(C8H5O4)}n, (L1 = 4-(1H-imidazol-1-yl)phenyl)methanone) has been synthesized under the solvothermal conditions. The structure has been determined by the single-crystal X-ray diffraction analysis and characterized by the infrared spectroscopy and elemental analysis. The crystal is crystallized in the monoclinic sp. gr. P21/c with the unit cell parameters a = 15.6387(3) Å, b = 8.0526(2) Å, c = 24.4791(6) Å, and β = 129.2350(10)°, Z = 2. The adjacent [Ni(H2O)2] units are linked by two bridging L1 ligands to form 1D looped chains, which are extended by the hydrogen bonds to yield a 3D framework.

Авторлар туралы

Shu-Wen Sun

Department of Applied Chemistry, Yuncheng University

Хат алмасуға жауапты Автор.
Email: sunsw0819@163.com
ҚХР, Yuncheng, 044000

Gao-Feng Wang

Department of Applied Chemistry, Yuncheng University

Email: sunsw0819@163.com
ҚХР, Yuncheng, 044000

Xiao Zhang

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage,
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Email: sunsw0819@163.com
ҚХР, Harbin, 150080

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