Nickel(II) Coordination Complex Constructed from Benzimidazole and Pyridine-2,6-dicarboxylate Co-ligands: Synthesis, Crystal Structure, Thermal Behavior, and Photoluminescence

Chen Ai-Hua; Wang Ai-Jian; Wang Ling; Sun Yu-Tong

doi:10.1134/S1063774518060081

Nickel(II) Coordination Complex Constructed from Benzimidazole and Pyridine-2,6-dicarboxylate Co-ligands: Synthesis, Crystal Structure, Thermal Behavior, and Photoluminescence

作者: Ai-Hua C.¹, Ai-Jian W.², Ling W.¹, Yu-Tong S.¹
隶属关系:
1. School of Chemistry and Chemical Engineering, Yancheng Institute of Technology
2. School of Chemistry and Chemical Engineering, Jiangsu University
期: 卷 63, 编号 6 (2018)
页面: 942-946
栏目: Structure of Organic Compounds
URL: https://journals.rcsi.science/1063-7745/article/view/193160
DOI: https://doi.org/10.1134/S1063774518060081
ID: 193160

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详细

A Ni(II) complex, [Ni(pydca)(bim)₃] (pydca = pyridine-2,6-dicarboxylate, bim = benzimidazole) has been prepared by hydrothermal synthesis. It is characterized by elemental analysis, IR and thermal analysis. The crystal structure is determined by single crystal X-ray diffraction. The mononuclear complexes are linked by N–H···O hydrogen bonds. The title complex has good thermal stability and exhibits good fluorescence properties in ethanol solution at room temperature.