Synthesis and Single Crystal X-Ray Structure of 3,5-Diphenyl-1-(phenylacetyl)-4,5-dihydro-1H-pyrazol
- Authors: Kansız S.1, Tınmaz F.2, İlhan İ.Ö.2, Sarıpınar E.2, Dege N.1
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Affiliations:
- Ondokuz Mayıs University, Faculty of Arts and Sciences, Department of Physics
- Erciyes University, Department of Chemistry, Faculty of Sciences
- Issue: Vol 63, No 6 (2018)
- Pages: 937-941
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/193149
- DOI: https://doi.org/10.1134/S1063774518060160
- ID: 193149
Cite item
Abstract
The molecule of the title pyrazole derivative, 3,5-diphenyl-1-(phenylacetyl)-4,5-dihydro-1H-pyrazol, C23H20N2O, is twisted. The compound crystallizes in the monoclinic sp. gr. I2/a with a = 15.3502(13) Å, b = 12.7576(8) Å, c = 19.625(2) Å, β = 106.639(7)°, and Z = 8. In the compound, the phenyl rings form dihedral angles of 12.01(13)°, 80.36(8)°, and 86.95(9)° with the mean plane of the pyrazole ring (r.m.s. deviation = 0.030 Å). The central pyrazole ring, which approximates an envelope conformation, is almost coplanar with one of the phenyl rings. The crystal packing is stabilized by weak intermolecular C–H···O hydrogen bonds.
About the authors
S. Kansız
Ondokuz Mayıs University, Faculty of Arts and Sciences, Department of Physics
Author for correspondence.
Email: sevgi.koroglu@omu.edu.tr
Turkey, Samsun, 55139
F. Tınmaz
Erciyes University, Department of Chemistry, Faculty of Sciences
Email: sevgi.koroglu@omu.edu.tr
Turkey, Kayseri, 38039
İ. Ö. İlhan
Erciyes University, Department of Chemistry, Faculty of Sciences
Email: sevgi.koroglu@omu.edu.tr
Turkey, Kayseri, 38039
E. Sarıpınar
Erciyes University, Department of Chemistry, Faculty of Sciences
Email: sevgi.koroglu@omu.edu.tr
Turkey, Kayseri, 38039
N. Dege
Ondokuz Mayıs University, Faculty of Arts and Sciences, Department of Physics
Email: sevgi.koroglu@omu.edu.tr
Turkey, Samsun, 55139