Email this article Synthesis, Crystal Structure, and Luminescence of Three-dimensional Cd(II) Coordination Polymer Generated from Benzopenone-2,4′-dicarboxylate and 1,4-Bis(1H-imidazol-1-yl)butane Mixed Ligands
- Authors: Xing J.N.1, Guo J.Z.1, Li B.1
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Affiliations:
- Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass
- Issue: Vol 63, No 4 (2018)
- Pages: 581-584
- Section: Structure of Organic Compounds
- URL: https://journals.rcsi.science/1063-7745/article/view/192670
- DOI: https://doi.org/10.1134/S1063774518040296
- ID: 192670
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Abstract
A new coordination polymer, namely, [Cd(L)(BIB)0.5]n (H2L = benzophenone-2,4′-dicarboxylic acid, BIB = 1,4-bis(1H-imidazol-1-yl)butane), was synthesized under hydrothermal condition. Single-crystal X-ray analysis reveals that two adjacent Cd(II) ions are bridged by four L2− ligands to form a two-dimensional layers, which are further connected by BIB to build a beautiful three-dimensional (3D) network. The luminescent and thermal properties of the compound are investigated.
About the authors
J. N. Xing
Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass
Email: libingzjfc@163.com
China, Lin’an, Zhejiang, 311300
J. Z. Guo
Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass
Email: libingzjfc@163.com
China, Lin’an, Zhejiang, 311300
B. Li
Zhejiang Provincial Key Laboratory of Chemical Utilization of Forestry Biomass
Author for correspondence.
Email: libingzjfc@163.com
China, Lin’an, Zhejiang, 311300
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