Diffusion of One-Dimensional Crystals in Channels of Single-Walled Carbon Nanotubes


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The transport of one-dimensional CuI crystals in channels of single-walled carbon nanotubes (SWCNTs) has been studied by high resolution electron microscopy. The diffusion kinetics has been investigated by counting the number of CuI atoms escaping from the nanotube channel. The diffusivity is calculated to be 6.8 × 10–21 m2/s, which corresponds to an activation-barrier height of ~1 eV/atom. A comparison with the theoretically estimated height of the energy barrier for molecular transport through a graphene layer is indicative of mass transfer through vacancy defects in graphene.

作者简介

V. Zhigalina

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics,”; National Research Centre “Kurchatov Institute,”; Centre for Surface and Vacuum Research (CSVR)

编辑信件的主要联系方式.
Email: v.zhigalina@gmail.com
俄罗斯联邦, Moscow, 119333; Moscow, 123182; Moscow, 119421

A. Kumskov

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics,”; National Research Centre “Kurchatov Institute,”; Centre for Surface and Vacuum Research (CSVR)

Email: v.zhigalina@gmail.com
俄罗斯联邦, Moscow, 119333; Moscow, 123182; Moscow, 119421

N. Falaleev

Moscow State University

Email: v.zhigalina@gmail.com
俄罗斯联邦, Moscow, 119992

A. Vasiliev

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics,”; National Research Centre “Kurchatov Institute,”; Centre for Surface and Vacuum Research (CSVR)

Email: v.zhigalina@gmail.com
俄罗斯联邦, Moscow, 119333; Moscow, 123182; Moscow, 119421

N. Kiselev

Shubnikov Institute of Crystallography, Federal Research Centre “Crystallography and Photonics,”

Email: v.zhigalina@gmail.com
俄罗斯联邦, Moscow, 119333

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