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Vol 40, No 2 (2018)

Production, Structure, Properties

Nucleation of the Plasticity at Nanodeformation of the Y3Al5O12 Yttrium-Aluminum Garnet

Dub S.N., Yavetskiy R.P., Belous V.A., Dolzhenkova E.F., Tolmacheva G.N., Sidletskiy O.T.

Abstract

The nanoindentation in the continuous stiffness measurement (CSM) mode was used to study the nucleation of the plasticity at the nanodeformation of the yttrium-aluminium garnet (YAG) having a low ((111) YAG single crystal after the annealing at the temperature of 1300°C) and a high (polycrystalline yttrium-aluminium garnet with a grain size of ~ 20 μm after the mechanical polishing) density of dislocations. For a sample having a high dislocations density a smooth elastoplastic transition was observed in the nanocontact as a result of the motion and multiplication of dislocations that are already present in the sample. For (111) YAG single crystal after annealing at the temperature of 1300°C an abrupt elastoplastic transition (pop-in) caused by a homogeneous nucleation of dislocations in the region under the contact was observed.

Journal of Superhard Materials. 2018;40(2):75-81
pages 75-81 views

Kinetics of the Surface Oxidation of Diamond Nanopowder, Modified with Tungsten by Chemical Adsorption from a Solution

Zabuga V.Y., Tsapyuk G.G., Kurylyak T.O., Bochechka O.O.

Abstract

The oxidation kinetics of the ACM5 0.1/0 statically synthesized diamond nanopowder in the presence of tungsten in the amounts of 1 and 5 wt %, introduced into the sample by wetting it with the (NH4)2WO4 water solution was investigated. It is established that at the chemical modification of a diamond nanopowder with tungsten by adsorption from a solution the inhibitory action of tungsten on the kinetics of the diamond oxidation also shows. This agrees with the suggested kinetic scheme of the reaction, which contains the stage of the diamond interaction with the gaseous tungsten oxide.

Journal of Superhard Materials. 2018;40(2):82-87
pages 82-87 views

High-Entropy Coatings—Structure and Properties

Gorban’ V.F., Andreev A.A., Shaginyan L.R., Firstov S.A., Karpets M.V., Danilenko N.I.

Abstract

Metal and nitride coatings of high-entropy alloys (HEA) having different phase compositions produced by different methods were investigated. It is shown that for the high-entropy coatings is characteristic the presence of the nanostructured state, which in parallel with the cluster structure provides hardness for metal coatings ~ 10–19 GPa; for nitride coatings are characteristic 50–60 GPa and the modulus of inelastic buckling more than 300 MPa. The relation of the lattice parameters, which are defined experimentally, to the parameter of the lattice of the most refractory metal in the HEA reflects the level of the elastic modulus relative to the theoretically possible both in the cast HEA and in metal coatings on their base.

Journal of Superhard Materials. 2018;40(2):88-101
pages 88-101 views

Formation of Superhard State of the TiZrHfNbTaYN Vacuum–Arc High-Entropy Coating

Beresnev V.M., Sobol’ O.V., Andreev A.A., Gorban’ V.F., Klimenko S.A., Litovchenko S.V., Kovteba D.V., Meilekhov A.A., Postel’nik A.A., Nemchenko U.S., Novikov V.Y., Maziilin B.A.

Abstract

Complex studies of the formation of the superhard state in the TiZrHfNbTaYN vacuum-arc high-entropy coating were carried out. Based on the approach of the structural surface engineering, the regularities of the formation of the triads composition–structure–physico-mechanical properties depending on the supplied potential displacement are established. It is shown that the increase of Ub at the formation of a coating leads to a decrease of the relative content of a light (Ti) and increase of a heavy (Ta, Hf) metal components, which is determined by radiationally stimulated processes in a near-surface region at the deposition. The formation of the single-phase state (based on the fcc of metal lattice) in the range Ubfrom–50 to–250 V and revealed the formation of the preferred orientation of the crystallites with the axis [111], which is perpendicular to the growth plane. The increase of the perfection of the texture with the [111] axis with increasing Ub is accompanied with an increase of the coatings hardness, which makes it possible to achieve the superhard state (H = 40.2 GPa) at Ub =–250 V.

Journal of Superhard Materials. 2018;40(2):102-109
pages 102-109 views

Thermal Analysis of FeCoCu Pre-Alloyed Powders Used for Diamond Tools

Xie D., Xiao L., Lin F., Pan X., Su Y., Fang X., Qi H., Chen C.

Abstract

By simulating the pressureless sintering process, the thermal effects of FeCoCu pre-alloyed powders have been investigated. According to the notions of the Kissinger method, the activation energies in the expansion-shrinkage conversion stage are analyzed. Results show that with Fe content increasing, the specimens’ specific heat capacity values present the increasing trend. The 25%Fe–15%Co–60%Cu specimens have negative enthalpy value at 10°C/min and 20°C/min heating rate but positive values at 30°C/min. For the specimens with lower Cu content, the enthalpies are always positive. It is established that both the specific heat capacity and enthalpy are larger when at higher heating rates. The activation energy of the 65%Fe–15%Co–20%Cu specimens is 10 times higher than that of the 25%Fe–15%Co–60%Cu specimens and the 45%Fe–15%Co–40%Cu specimens.

Journal of Superhard Materials. 2018;40(2):110-117
pages 110-117 views

Investigation on the Static Fatigue Mechanism and Effect of Specimen Thickness on the Static Fatigue Lifetime in WC–Co Cemented Carbides

Chen D., Yao L., Chen Z., Wang H., Peng W.

Abstract

The static fatigue mechanism and effect of specimen thickness on static fatigue lifetime for four WC–Co cemented carbides were studied with different binder contents and carbide grain sizes. Static fatigue tests under three-point bend loading were conducted on different sized specimens. The fracture surfaces of rupture specimens were examined by scanning electron microscopy to investigate the static fatigue micromechanisms. Experimental results show that microcracks nucleate from defects or inhomogeneities and the connection of microcracks produces a main crack. The main crack propagates rapidly, resulting in the fracture of specimens. The extension of static fatigue lifetime with the increase of specimen thickness is due to the decrease of plastic zone size near the crack tip and relevant energy change during the crack growth. The effect of specimen thickness on static fatigue lifetime is much greater for cemented carbides with larger WC grain size or higher cobalt content, which is attributed to operative toughening mechanisms.

Journal of Superhard Materials. 2018;40(2):118-126
pages 118-126 views

Influence of High Pressure and Temperature on the Structure and Properties of the WC–6Co Hard Alloy

Andreiev I.V., Gnatenko I.O., Lysovenko S.O., Gargin V.G.

Abstract

The results are presented of the barothermal treatment studies of a WC–6Co hard alloy at high pressure (7 GPa). It is shown that such a treatment of hard alloy leads to the deterioration of the basic physico-mechanical characteristics, specifically the strength at the contact, and the coercive force, which is stipulated by the increase of the defects amount in the structure of the carbide phase of the hard alloy.

Journal of Superhard Materials. 2018;40(2):127-130
pages 127-130 views

Investigation of Machining Processes

The Influence of Surface Roughness of Cutting Inserts Made of Diamond–Tungsten Carbide Composite on Cutting Forces and Machining Quality in Turning Aluminum Alloys and Brass

Devin L.N., Stakhniv N.E., Mel’niichuk Y.A.

Abstract

The paper addresses the effect of face roughness of cutting inserts made of diamond–tungsten carbide nanocomposite on cutting forces, vibration, and machined surface quality in finish turning of aluminum alloys and brass. The authors have substantiated the optimal cutting conditions to produce workpiece surfaces with the minimum roughness and waviness.

Journal of Superhard Materials. 2018;40(2):131-137
pages 131-137 views

The Process of Abrasive Machining as a Friction Interaction Between Dissimilar Materials

Lavrinenko V.I., Solod V.Y.

Abstract

The portion of friction energy in the abrasive machining process has been assessed for various cutting-tool materials machined, and some methods for decreasing friction in grinding with superabrasive wheels, especially reducing friction on the bond surface of superabrasive wheels.

Journal of Superhard Materials. 2018;40(2):138-142
pages 138-142 views

Tools, Powders, Pastes

The Amount of Impurity Elements in Diamond-Containing Soot and Detonation Nanodiamonds upon Nitric Acid Treatment

Dolmatov V.Y.

Abstract

The influence of the explosive charge shell composition and the explosive charge modification by various compounds on the yield of DND and DS, content of impurities and their elemental composition has been studied. With proper choice compounds, one can increase the DS yield to 18.6 wt % and the DND yield to 7.6 wt %, reduce the amount of impurities down to 0.23 wt % in DS and to 0.3 wt % in DND. The phosphorus concentration was brought to 0.665 wt % in DS and to 0.244 wt % in DND; the boron content was brought to 0.96 wt % in DS and to 0.472 wt % in DND.

Journal of Superhard Materials. 2018;40(2):143-154
pages 143-154 views

Erratum

Erratum to: “Mechanism of Functionalization of the Surfaces of Detonation Nanodiamonds: Mass-Spectrometric Investigation”

Pozdnyakov A.O., Voznyakovskii A.P., Kalinin A.V.

Abstract

We would like to inform you that a sad mistake was made in one of our articles in “Journal of Superhard Materials”, 2018, vol. 40, no. 1, pp. 16–20. The article is “Mechanism of Functionalization of the Surfaces of Detonation Nanodiamonds: Mass-Spectrometric Investigation” by A. O. Pozdnyakov, A. P. Voznyakovskii, and A. V. Kalinin.

Journal of Superhard Materials. 2018;40(2):155-155
pages 155-155 views