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Vol 39, No 3 (2017)

Production, Structure, Properties

Calculation of the temperature distribution at the HPHT growing of diamond single crystals in cells with two growth layers

Burchenia A.V., Lysakovs’kii V.V., Gordeyev S.O., Ivakhnenko S.O., Kutsai A.M., Suprun O.M.

Abstract

Finite element method was used to calculate the distribution of temperatures in growth cells of the toroid TC-40 -type HPA. The experimental investigations of the process of growing type IIa diamond single crystals were performed in high-pressure cells with two growth layers. It is shown that in using the cell materials having appropriate properties and defined configuration of the system of the resistive heating the temperature gradients are 5.4–5.6°C/mm and the growth rate is 2.46 mg/h. The total weight of obtained structurally perfect type IIa diamond single crystals in the upper and lower growth layers is 1.18 and 1.13 carats, respectively, the nitrogen content in all grown crystals is 1–3 ppt.

Journal of Superhard Materials. 2017;39(3):149-154
pages 149-154 views

Superhard pcBN tool materials with Ti3SiC2 MAX-phase binder: Structure, properties, application

Kolabylina T., Bushlya V., Petrusha I., Johansson D., Ståhl J., Turkevich V.

Abstract

Superhard cutting tool materials were sintered in cBN–(Ti3SiC2–TiC) system via high pressure–high temperature method. Sintering was performed under the pressure 8 GPa in the 1400–2400°C temperature range. The initial mixtures of three compositions were chosen with 90, 80 and 60 vol % cBN. The mixtures were prepared by mixing cBN (1–3 μm) and Ti3SiC2–TiC (< 2 μm). It was found, that upon sintering, the compositions of the obtained samples differed from the initial mixtures in all cases as a result of chemical reactions. Microstructure observations, phase composition estimation, and mechanical properties of the obtained tool materials were carried out. The results indicate that both the varying cBN content and the applied sintering conditions have a direct effect on the structure, properties, and kinetics of reactions.

Journal of Superhard Materials. 2017;39(3):155-165
pages 155-165 views

Production and mechanical properties of high-entropic carbide based on the TiZrHfVNbTa multicomponent alloy

Gorban’ V.F., Andreyev A.A., Kartmazov G.N., Chikryzhov A.M., Karpets M.V., Dolomanov A.V., Ostroverkh A.A., Kantsyr E.V.

Abstract

The possibility of producing coatings of high entropic carbide by scattering multicomponent alloy in plasma of compressed vacuum–arc discharge has been shown. It is defined that the hardness of coatings from high-entropic carbide based on TiZrHfVNbTa multicomponent alloy is 43–48 GPa and exceeds the hardness of monocarbides of metals that enter into the composition of the alloy. The friction coefficient for the carbide high-entropic coating based on the TiZrHfVNbTa alloy at the loads 2.2 to 5.2 N is 0.14–0.16.

Journal of Superhard Materials. 2017;39(3):166-171
pages 166-171 views

Influence of the high-temperature annealing on the structure and mechanical properties of vacuum–arc coatings from Mo/(Ti + 6 wt % Si)N

Beresnev V.M., Klimenko S.A., Sobol’ O.V., Litovchenko S.V., Pogrebnjak A.D., Srebnyuk P.A., Kolesnikov D.A., Meilekhov A.A., Postel’nik A.A., Nemchenko U.S.

Abstract

Scanning electron microscopy with energy dispersive element microanalysis, X-ray structural analysis, and microindentation were used to study the effect of the deposition conditions in a reactive nitrogen atmosphere on the growth morphology, phase composition, structure, and microhardness of vacuum–arc multilayer coatings produced by the evaporation of cathodes from Mo and (Ti + 6 wt % Si) both after their deposition and after high-temperature annealing. It has been established that the use of the composite cathode of Ti and Si allows the formation of the structure state inclined to ordering to form a two-phase compound from TiN and Ti5Si3 at high-temperature annealing. In this case the coating hardness increases to a value higher than 45 GPa.

Journal of Superhard Materials. 2017;39(3):172-177
pages 172-177 views

Investigation of Machining Processes

Characterization of tool wear when machining alloy 718 with high-pressure cooling using conventional and surface-modified WC–Co tools

Hoier P., Klement U., Tamil Alagan N., Beno T., Wretland A.

Abstract

Coolant supplied by high pressure into the cutting zone has shown the lower thermal loads on the tool when machining difficult-to-cut materials as the Alloy 718. In this study, we investigate how the combination of high-pressure cooling and tool–surface modifications can lead to further improvements regarding tool life. The general approach is to enhance the coolant–tool interaction by increasing the contact area. Therefore, we machined cooling features into flank and rake faces of commercially available cemented tungsten carbide inserts. In this way, the surface area was increased by ~ 12%. After the cutting tests, the tools were analyzed by scanning electron microscopy combined with energy-dispersive X-ray spectroscopy. Compared with conventional tools, the tool modifications reduced the flank wear by 45% for the investigated cutting parameters. Furthermore, we were able to significantly increase the cutting speed and feed rate without failure of the tool. The investigated surface modifications have great potential to enhance the productivity of metal cutting processes.

Journal of Superhard Materials. 2017;39(3):178-185
pages 178-185 views

Determination of grinding conditions for renewal of a wheel cutting ability allowing for its variation during the machining process

Matyukha P.G., Poltavets V.V.

Abstract

The authors discuss the determination of rigid-mode grinding conditions with a periodic electric discharge action on the wheel working surface in a separate zone, taking into account the in-process variation of the wheel cutting ability. The calculation is based on the mathematical relations that describe variation of the wheel cutting ability in elastic-mode infeed grinding with a constant workpiece-to-wheel pressing force, where the process kinematics is similar to that of the rigid-mode grinding. The workpiece speed is determined for a specified machined surface roughness. The workpiece-to-wheel pressing force is chosen such that the surface layer of the workpiece material should undergo no phase-structural transformations. The variations of the wheel cutting ability during the rigid-mode grinding are taken into account through the use of the equations that describe the variations of the wheel's current limited cutting ability in the elastic-mode grinding. Based on the discussion of various methods of calculation of one of the grinding parameters—depth of cut—the authors have found its value ensuring that no phase-structural transformations will occur in the surface layer of the workpiece material under maximum feasible removal rates.

Journal of Superhard Materials. 2017;39(3):186-191
pages 186-191 views

Tools, Powders, Pastes

Influence of tool material and tool wear on tool temperature in hard turning reconstructed via inverse problem solution

Kryzhanivskyy V., Bushlya V., Gutnichenko O., M’Saoubi R., Ståhl J.

Abstract

In this work the cutting tool temperature distribution that develops during turning of hardened cold-work tool steel is modeled on the basis of experimental data. The data obtained from a series of thermocouples, placed on a PCBN insert, into an anvil, and into a toolholder, were used as the input for the model. An inverse problem was solved, where the heat fluxes were computed. The temperature distribution was modeled for the case of new tools, as well as for the case of its development in the course of a tool wear. The reconstructed temperature distributions were in good agreement with the measured data. The heat flux through rake face was found to be reducing with the decrease of thermal conductivity of the tool material.

Journal of Superhard Materials. 2017;39(3):192-202
pages 192-202 views

Electrodeposited diamond coating with protection by diamond micron powder in a dressing tool. Part 2. Tool performance

Sheiko M.N., Maksimenko A.P., Bologov P.I.

Abstract

The paper compares the results of tool life testing of dressing rollers with conventional electrodeposited diamond coating (EDC) and with protected EDC. The protection of EDC by diamond powder is demonstrated to extend the effective tool life (for the tools manufactured by the electroforming process) by 90% and the total tool life (i.e., till eventual failure of EDC) by 125%. The time history of the diamond grain depth in the bond has been theoretically clarified and this parameter has been found to be related to wear characteristics of the bond and diamond grains.

Journal of Superhard Materials. 2017;39(3):203-209
pages 203-209 views

The fundamentals of synthesis of modified layers on cutting-tool hard alloys

Samotugin S.S., Lavrinenko V.I., Kudinova E.V., Samotugina Y.S., Ivanov V.I.

Abstract

A methodology has been elaborated for controlling the structure formation in cutting-tool hard alloys during the plasma modification of their surfaces in order to produce an ultradispersed structure in the surface layer providing a high level of performance characteristics. The paper presents a block diagram of synthesis of modified layers with an ultradispersed structure, which includes a combination of theoretical, experimental, and technological investigations. The tool life testing of the modified tools has been carried out.

Journal of Superhard Materials. 2017;39(3):210-215
pages 210-215 views

Letters to the Editor

Structure and properties of hot-pressed materials based on AlB12C2

Prikhna T.A., Barvitskyi P.P., Dub S.N., Muratov V.B., Karpets M.V., Moshchil’ V.E., Ponomarev S.S., Vasil’ev A.A.

Abstract

The results are presented on the investigation of the structure and mechanical properties of hot-pressed materials based on AlB12C2 powders of sizes 50–150 nm. It is shown that the consolidated materials having mechanical properties comparable with boron carbide may be produced at essentially lower (by 270–300°C) sintering temperatures. It has been established that the heating rate at compressing affects the stoichiometry of the impurity phase containing Al, B, O, which define the difference in mechanical properties of the materials (a decrease of the heating rate results in the insignifical decrease of the material hardness and increase of the fracture toughness).

Journal of Superhard Materials. 2017;39(3):216-219
pages 216-219 views