Peculiarities of Serpentine Decomposition in the Presence of Alkaline Chloride: Raman Study at High Pressure and Temperature


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In situ Raman spectroscopy combined with a resistively heated diamond anvil cell was used to study the behavior of serpentine (chrysotile) Mg3Si2O5(OH)4 in the presence of NaCl at 100–400°С and 10 kbar. Low H2O activity leads to a decrease in the dehydration temperature by about 200°C compared to a salt-free system, as well as the formation of only anhydrous products.

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A. Likhacheva

Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences; Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: alih@igm.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

S. Goryainov

Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences

Email: alih@igm.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

S. Rashchenko

Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences; Budker Institute of Nuclear Physics, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: alih@igm.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090; Novosibirsk, 630090

O. Safonov

Institute of Experimental Mineralogy, Russian Academy of Sciences; Moscow State University

Email: alih@igm.nsc.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432; Moscow, 119991

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