AFM Study of Potassium–Ammonium Hydrogen Sulfates at Lower Temperatures


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Abstract

Surfaces of the natural cleavage of water-soluble single crystals (K0.43(NH4)0.57)3H(SO4)2 is studied via atomic force microscopy. It is shown that ultrafine details of nanorelief (pits and hills with stable parameters of height (depth) of ~0.7 nm form on the surfaces of crystals) correspond to 1/3 с in a unit cell. A phase transition (from paraelectric to ferroelectric) is detected in the (K0.43(NH4)0.57)3H(SO4)2 crystal via microscopy of the piezoelectric response as the temperature falls from 296 to 282 K.

About the authors

R. V. Gainutdinov

Federal Scientific Research Center Crystallography and Photonics, Russian Academy of Sciences

Email: alla@ns.crys.ras.ru
Russian Federation, Moscow, 119333

A. L. Tolstikhina

Federal Scientific Research Center Crystallography and Photonics, Russian Academy of Sciences

Author for correspondence.
Email: alla@ns.crys.ras.ru
Russian Federation, Moscow, 119333

E. V. Selezneva

Federal Scientific Research Center Crystallography and Photonics, Russian Academy of Sciences

Email: alla@ns.crys.ras.ru
Russian Federation, Moscow, 119333

I. P. Makarova

Federal Scientific Research Center Crystallography and Photonics, Russian Academy of Sciences

Email: alla@ns.crys.ras.ru
Russian Federation, Moscow, 119333

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