Phase Composition and Magnetic Properties of Fe2O3–FeO–Gd2O3 Powders after High-Energy Ball Milling and Thermal Treatment


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Abstract

Comprehensive studies of powders with a nominal composition of 90% [43% Fe2O3–57% FeO]–10% Gd2O3 are performed via scanning electron microscopy, microscopic X-ray spectral and phase analysis, differential scanning calorimetry, and measuring hysteresis properties. It is shown that the main phases in the powders after high-energy ball milling are magnetite (Fe3O4) and an amorphous phase; in addition, the powders contain about 2 vol % wustite (FeO) and less than 1 vol % orthoferrite (GdFeO3). Trends of changes in the phase composition, structure, and hysteresis properties of the annealed powders are identified.

About the authors

S. V. Salikhov

National University of Science and Technology (MISiS)

Author for correspondence.
Email: salta_150@inbox.ru
Russian Federation, Moscow, 119049

S. K. Toleukhanova

National University of Science and Technology (MISiS)

Email: salta_150@inbox.ru
Russian Federation, Moscow, 119049

I. G. Bordyuzhin

National University of Science and Technology (MISiS)

Email: salta_150@inbox.ru
Russian Federation, Moscow, 119049

A. G. Savchenko

National University of Science and Technology (MISiS)

Email: salta_150@inbox.ru
Russian Federation, Moscow, 119049

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