Email this article Ferromagnetism of localized and itinerant electrons in two-dimensional organometallic networks
- Authors: Ovanesyan N.S.1, Nikitina Z.K.1, Makhaev V.D.1
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Affiliations:
- Institute of Problems of Chemical Physics
- Issue: Vol 81, No 7 (2017)
- Pages: 855-859
- Section: Article
- URL: https://journals.rcsi.science/1062-8738/article/view/185131
- DOI: https://doi.org/10.3103/S1062873817070206
- ID: 185131
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Abstract
The magnetic properties of two-dimensional (2D) molecular magnets with compositions (NPn4)[FeIIFeIII(C2O4)3] and ((NPn4)2)[Fe2(C6Cl2O4)3] are studied via 57Fe Mössbauer spectroscopy. It is shown that substituting the bridging oxalate ligand (C2O4)2− for chloranilate (C6Cl2O4)2− having the same coordination ability produces fundamental changes in the ground state, turning it from a ferrimagnetic insulator to a ferromagnetic conductor.
About the authors
N. S. Ovanesyan
Institute of Problems of Chemical Physics
Author for correspondence.
Email: kolya44@mail.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
Z. K. Nikitina
Institute of Problems of Chemical Physics
Email: kolya44@mail.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
V. D. Makhaev
Institute of Problems of Chemical Physics
Email: kolya44@mail.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432
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