Email this article Ionic polymerization in an electric field and consequences of the spatial redistribution of growing macroions and counterions
- Authors: Ponomarenko A.T.1, Tameev A.R.2, Shevchenko V.G.1
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Affiliations:
- Enikolopov Institute of Synthetic Polymeric Materials
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 80, No 9 (2016)
- Pages: 1131-1133
- Section: Proceedings of the 23rd International Scientific Conference “Relaxation Phenomena in Solids,” Dedicated to the Centenary of the Birth of V.S. Postnikov
- URL: https://journals.rcsi.science/1062-8738/article/view/184826
- DOI: https://doi.org/10.3103/S1062873816090380
- ID: 184826
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Abstract
Reaction mixtures in which polymerization processes proceed are investigated both in an electric field and under classical conditions. The observed kinetic effects are explained using a model concept of the primary contribution to the revealed field effects from the dissociation of ion pairs due to the spatial redistribution of ions. This model may be applied to both cationic and anionic polymerization processes.
About the authors
A. T. Ponomarenko
Enikolopov Institute of Synthetic Polymeric Materials
Author for correspondence.
Email: anapon@ispm.ru
Russian Federation, Moscow, 117393
A. R. Tameev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: anapon@ispm.ru
Russian Federation, Moscow, 119991
V. G. Shevchenko
Enikolopov Institute of Synthetic Polymeric Materials
Email: anapon@ispm.ru
Russian Federation, Moscow, 117393
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