Effect of polyene chain length on the parameters of intra- and intermolecular interactions between all-trans diphenyl polyenes

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Abstract

The parameters of Franck–Condon and Herzberg–Teller interactions that form the fine-structure spectra of all-trans diphenyl polyenes in n-paraffin solutions at 4.2 K are analyzed. The effect the length of a polyene chain has on the emergence of benzene fragment bands is considered for four all-trans-diphenyl polyene compounds that differ by the number of π-conjugated bonds in the polyene chain.

About the authors

V. V. Kompaneez

Moscow State Pedagogical University

Author for correspondence.
Email: kompaneez@gmail.com
Russian Federation, Moscow, 119571

I. A. Vasilieva

Moscow State Pedagogical University

Email: kompaneez@gmail.com
Russian Federation, Moscow, 119571

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