Effect of polyene chain length on the parameters of intra- and intermolecular interactions between all-trans diphenyl polyenes
- Authors: Kompaneez V.V.1, Vasilieva I.A.1
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Affiliations:
- Moscow State Pedagogical University
- Issue: Vol 80, No 7 (2016)
- Pages: 848-854
- Section: Proceedings of the XII International Readings on Quantum Optics (Moscow–Troitsk, August 11–16, 2015)
- URL: https://journals.rcsi.science/1062-8738/article/view/184698
- DOI: https://doi.org/10.3103/S1062873816070169
- ID: 184698
Cite item
Abstract
The parameters of Franck–Condon and Herzberg–Teller interactions that form the fine-structure spectra of all-trans diphenyl polyenes in n-paraffin solutions at 4.2 K are analyzed. The effect the length of a polyene chain has on the emergence of benzene fragment bands is considered for four all-trans-diphenyl polyene compounds that differ by the number of π-conjugated bonds in the polyene chain.
About the authors
V. V. Kompaneez
Moscow State Pedagogical University
Author for correspondence.
Email: kompaneez@gmail.com
Russian Federation, Moscow, 119571
I. A. Vasilieva
Moscow State Pedagogical University
Email: kompaneez@gmail.com
Russian Federation, Moscow, 119571
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