Email this article Synthesis and electrical properties of new perovskite-like AMn3V4O12 (A = Ca, Ce, and Sm) compounds
- Authors: Kadyrova N.I.1, Zaynulin Y.G.1, Tyutyunnik A.P.1, Melnikova N.V.2, Mirzorakhimov A.A.2
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Affiliations:
- Institute of Solid State Chemistry, Ural Branch
- Institute of Natural Sciences
- Issue: Vol 80, No 6 (2016)
- Pages: 620-623
- Section: Proceedings of the Interdisciplinary Symposium “Ordering in Minerals and Alloys” OMA-18 and Proceedings of the International Interdisciplinary Symposium “Order, Disorder, and Properties of Oxides” ODPO-18
- URL: https://journals.rcsi.science/1062-8738/article/view/184431
- DOI: https://doi.org/10.3103/S1062873816060149
- ID: 184431
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Abstract
AMn3V4O12 (A = Ca, Ce, and Sm) compounds with a perovskite structure are synthesized at high pressures and temperatures. The crystalline structure of these compounds (space group \(Im\bar 3\)Z = 2) is determined via X-ray analysis. If ions in the A sublattice are changed in the order Ca2+–Sm3+–Ce3+, the valence is redistributed from Ca2+Mn32+V44+O12 to Sm3+Mn32+V43.75+O12, and to Ce3+Mn32+V43.75+O12. The temperature dependences of the electrical resistivity are studied.
About the authors
N. I. Kadyrova
Institute of Solid State Chemistry, Ural Branch
Author for correspondence.
Email: kadyrova@ihim.uran.ru
Russian Federation, Yekaterinburg, 620990
Yu. G. Zaynulin
Institute of Solid State Chemistry, Ural Branch
Email: kadyrova@ihim.uran.ru
Russian Federation, Yekaterinburg, 620990
A. P. Tyutyunnik
Institute of Solid State Chemistry, Ural Branch
Email: kadyrova@ihim.uran.ru
Russian Federation, Yekaterinburg, 620990
N. V. Melnikova
Institute of Natural Sciences
Email: kadyrova@ihim.uran.ru
Russian Federation, Yekaterinburg, 620000
A. A. Mirzorakhimov
Institute of Natural Sciences
Email: kadyrova@ihim.uran.ru
Russian Federation, Yekaterinburg, 620000
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