Kinetics of mechanochemical dissolution of chromium in iron


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Abstract

The kinetics of solid Fe–Cr solution formation has been studied during mechanical alloying of Fe and Cr powders taken in an atomic ratio of 80: 20. X-ray diffraction and Mössbauer spectroscopy data have been analyzed within the framework of the energetic approach. It has been established that, in this system, reaction product yield N is related to mechanical energy dose D and specific surface area S of Fe nanograin boundaries in an ideal manner: N ~ D2 at S ~ D and N ~ D at S = const.

About the authors

E. P. Yelsukov

Physicotechnical Institute, Ural Branch

Email: e_yelsukov@mail.ru
Russian Federation, ul. Kirova, 132, Izhevsk, 426000

A. L. Ul’yanov

Physicotechnical Institute, Ural Branch

Email: e_yelsukov@mail.ru
Russian Federation, ul. Kirova, 132, Izhevsk, 426000

D. A. Kolodkin

Physicotechnical Institute, Ural Branch

Email: e_yelsukov@mail.ru
Russian Federation, ul. Kirova, 132, Izhevsk, 426000

V. E. Porsev

Physicotechnical Institute, Ural Branch

Author for correspondence.
Email: e_yelsukov@mail.ru
Russian Federation, ul. Kirova, 132, Izhevsk, 426000

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