Solution-combustion synthesis of MZrO3 zirconates (M = Ca, Sr, Ba) in open reactor: Thermodynamic analysis and experiment


Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Solution-combustion synthesis (SCS) of MZrO3 zirconates (M = Ca, Sr, Ba) in an open reactor with glycine as a fuel was studied both experimentally and theoretically. Calculated thermal effects of the above SCS reactions were found to reasonably agree with experiment. The measured thermal effects of SCS reactions (ΔTmax) as a function of fuel/oxidant ratio (φ) exhibited a maximum within the range φ = 0.9–1.3 arising due to increasingly growing radiative heat loss from the open surface of burning reactive mixture. The occurrence of self-sustained SCS reactions yielding CaZrO3, SrZrO3, and BaZrO3 was found possible for φ ≥ 0.4, 0.3, and 0.4, respectively.

Sobre autores

Sh. Khaliullin

Institute of Solid State Chemistry

Autor responsável pela correspondência
Email: shamil58@rambler.ru
Rússia, Yekaterinburg, 620990

V. Zhuravlev

Institute of Solid State Chemistry

Autor responsável pela correspondência
Email: zhvd@ihim.uran.ru
Rússia, Yekaterinburg, 620990

V. Bamburov

Institute of Solid State Chemistry

Email: zhvd@ihim.uran.ru
Rússia, Yekaterinburg, 620990

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML

Declaração de direitos autorais © Allerton Press, Inc., 2017