Solution-combustion synthesis of oxide nanoparticles from nitrate solutions containing glycine and urea: Thermodynamic aspects


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Solution-combustion synthesis (SCS) of nanoparticles was characterized by the temperature effect (ΔTad) calculated upon neglect by the temperature dependence of heat capacity. Thus calculated ΔTad values were found to be a linear function of the inverse radius of metal ions. Our calculations have shown that SCS reactions may yield not only oxides but also hydroxides and carbonates. Suggested was a simple formula for evaluating the ΔTad values attained in SCS of complex oxides.

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Sh. Khaliullin

Institute of Solid State Chemistry, Ural Branch

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Email: khaliullin@ihim.uran.ru
俄罗斯联邦, ul. Pervomaiskaya 91, Yekaterinburg, 620990

V. Zhuravlev

Institute of Solid State Chemistry, Ural Branch

Email: khaliullin@ihim.uran.ru
俄罗斯联邦, ul. Pervomaiskaya 91, Yekaterinburg, 620990

V. Bamburov

Institute of Solid State Chemistry, Ural Branch

Email: khaliullin@ihim.uran.ru
俄罗斯联邦, ul. Pervomaiskaya 91, Yekaterinburg, 620990

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