Email this article A Hamiltonian for the electron-vibrational-rotational problem in the theory of molecules
- Authors: Gribov L.A.1
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Affiliations:
- Vernadsky Institute of Geochemistry and Analytical Chemistry
- Issue: Vol 61, No 3 (2016)
- Pages: 105-107
- Section: Physics
- URL: https://journals.rcsi.science/1028-3358/article/view/191019
- DOI: https://doi.org/10.1134/S1028335816030034
- ID: 191019
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Abstract
On the basis of the use of the generalized (natural) coordinates for the description of electrons and nuclei and the representation of a molecule as a stable geometrical figure, where the electrons and nuclei interact by Coulomb’s law, while nuclei with nuclei interact elastically, a Hamiltonian describing simultaneously the electron and vibrational states and the rotations of a molecule as a whole is proposed.
About the authors
L. A. Gribov
Vernadsky Institute of Geochemistry and Analytical Chemistry
Author for correspondence.
Email: l_gribov@mail.ru
Russian Federation, Moscow, 117975
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