Vol 467, No 2 (2016)

The first results of U–Pb dating of detrital zircons from Upper Ordovician sandstones of the Bashkir uplift in the Southern Urals and U–Pb isotopic ages available for detrital zircons from six stratigraphic levels of the Riphean–Paleozoic section of this region are discussed. It is established that the long (approximately 1.5 Ga) depositional history of sedimentary sequences of the Bashkir uplift includes a peculiar period lasting from the Late Vendian to the Emsian Age of the Early Devonian (0.55–0.41 Ga). This period is characterized by the following features: (1) prevalence of material from eroded Mesoproterozoic and Early Neoproterozoic crystalline complexes among clastics with ages atypical of the Volga–Urals segment of the East European Platform basement; (2) similarity of age spectra obtained for detrital zircons from different rocks of the period: Upper Vendian–Lower Cambrian lithic sandstones and Middle Ordovician substantially quartzose sandstones.

Investigation of the distribution of basalts, dolerites, and tuffs in the Kanin–Timan–Pechora large igneous province was completed by generalization of data of geological surveys and analysis of the data of deep drilling. The province appears like a nonisometric ellipse and extends northwestward for a distance of nearly 850 km at the width of 250–500 km. Its area is nearly 285 000 km². The area of the volcanic rocks is about 85 500 km². The volume of eruptive material alone could be equal to 1000–1200 km³. The age of formation of the traps corresponds to the late period of activity of the process and was less than 7 mln. y. The formation of the province was result of the action of short-lived and low intensity plumes. But it was one of the episodes of the Late Devonian superplume event in the East European platform. The province is separated by an amagmatic area from neighboring magmatic provinces of the same age. The distance between borders of the provinces is 200–400 km.

Anomalous concentrations of numerous major and minor elements significantly exceeding the threshold limit values (TLV) for drinking water were registered in the area of the Tyrnyauz Tungsten–Molybdenum Combine (TTMC). The maximal excess of the TLV (by one or two orders of magnitude) were obtained for Mo (up to 11 mg/L), W (4.4 mg/L), As (1.5 mg/L), Mn (8.4 mg/L), and Tl (up to 3.3 μg/L) in water of the Bolshoi Mukulan Brook flowing through the mines and three brooks flowing out from the base of the embankment of the tailing store no. 1. They are the major pollutants for water of the Baksan River. Upon flowing out to the plain, water of the Baksan River shows significant excess of the TLVs (in summer) for Al, Fe, Mn, Be, Si, Ti, Tl, and Hg.

The distribution of REEs and some minor elements in tourmalines of different associations and deposits of the Russian Far East is studied by the methods of ICP-MS, ICP-MS with laser ablation and scanning electron microscopy. The duality of REE speciation in tourmaline is established: in high-temperature varieties, most REEs (mainly HREEs) are incorporated in rare minerals (monazite, xenotime, zircon, and F–Ce–Y carbonate), whereas hydrothermal ores are characterized by isomorphic incorporation of LREEs in the mineral structure, as well as by a fine admixture of zircon at the expense of detrital clasts in flyschoid rocks with the zones of tourmalinization.

Newly obtained data from microscopic, geochemical, and thermomagnetic studies of the large Kolyma fulgurite are presented here: the fulgurite was formed in the Holocene as a result of lightning affected black shale alluvium. The composition is very close to that of glass formed from a melt. The glass has elevated concentrations of Y, Zr, Nb, and REEs. The newly formed mineral phases have been identified: those are Al–Si glass, α-cristobalite, moissanite, native iron with a phosphorus admixture, nickel-less shreibersite (?), troilite, and possibly cohenite. The formation of these minerals is related to the melt fractionation and the effects of element concentration and segregation of ore components under conditions of the rock melting caused by the effect of high-energy plasma (lightning strike).

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.

A direct correlation was shown for the first time between mosaic irisation patterns in synthetic and natural precious opals (from Australia, Ethiopia, Honduras, Slovakia, and Russia) and their frustumational (lump or mosaic–cluster) inner structure by means of photoluminescence, X-ray phase analysis, IR and Raman spectroscopy, and scanning electron microscopy.

The results of analysis of synchronous instrumental observations of seismic oscillations and the intensity of the electric field at the Earth’s surface under the conditions of the mid-latitude Mikhnevo Geophysical Observatory of the Institute of Geosphere Dynamics, Russian Academy of Sciences (IGD RAS) are presented. The results provide evidence that the seismoelectric effect exists in the influence zone of the deep tectonic structure, which is clearly seen in the records when strong perturbations caused by other electric field sources do not exist (propagation of atmospheric fronts, thunderstorm events, formation of eddy structures in the atmosphere, etc.). For the first time, a quantitative relation between the amplitudes of the seismic and induced electric signals under specific conditions was obtained.

We analyzed directed couplings between the variations in the global surface temperature and modes of the natural climatic variability: the El NiñoLa Niña (ENSO) quasi-periodical phenomena and the long-period Atlantic Mutidecadal Oscillation (AMO) based on the data for 1870–2014. According to the quantitative estimates based on the monthly and annual mean data, the initial data, and the 10-year mean remote data, the most pronounced impact of the ENSO on the global surface temperature and the AMO was found. A weaker bidirectional coupling between the global surface temperature and the AMO is also pronounced. The analysis using running windows revealed an alternating effect of the ENSO and AMO on the variations in the global surface temperature related to the AMO phases.

The revealed regularities in the behavior of the electric conductivity of the geological medium on the Shipunskii Peninsula are in qualitative agreement with the seismicity variations in the Kamchatka region. The possible nature of variations in deep conductivity is considered.

Applying the methods of absolute geochronology and lithology, it has been established that the average sedimentation rate in the Sea of Azov over the last 6000 years (Ancient and New Azov times) varied from 0.2 to 2.0 mm/year. Its minimum values are confined to transit and sediment-starved zones coinciding with the directions of the main marine currents. It has been indicated that changes in the water level of the Sea of Azov occur with lag relative to landscape–climate phases. The obtained data confirm the relation between marine and terrestrial processes occurring in the Sea of Azov region: transgressive phases are preceded by general humidification in adjacent regions, while regressive phases correlate with climate aridization. The biostratigraphic analysis of the Holocene sections examined reveals the unstable behavior of the sea level during their formation. The results of diatom analysis confirm development of the Phanagoria and Korsun Regressions and Nymphea Transgression. Frequent fluctuations of the Sea of Azov the level determined the rhythmical structure of the sedimentary sequence saturated with autochthonous and allochthonous organic matter.

The features of the intrasecular changes in the level of the largest lakes of Russia (Baikal, Ladoga, Onego, and the inland Caspian Sea) are jointly considered for the first time on the basis of the long-term data measured in the 20th–21st centuries. The influence of climate and anthropogenic factors is considered to improve the forecast of the level of lakes.

The carbonate system of waters of the inner, middle, and outer shelves was studied for a long period in the eastern part of the Laptev Sea. It is shown that the inner and middle shelves is a heterotrophic province and is a source of CO₂ to the atmosphere during August–September. The average CO₂ flux is 7.9 mmol m^–2 day^–1 and during one month waters of inner and middle shelves release into the atmosphere up to 0.7 Tg of carbon (C). The outer part of the shelf absorbs up to ~0.1 Tg C at an average rate of 3.9 mmol m^–2 day^–1 during the month. Generally, the ice-free zone of the eastern shelf of the Laptev Sea is a source of CO₂ in the studied season: the amount of C released into the atmosphere within a month is ~0.6 Tg.