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Composition of Hydrocarbons in Synthetic Diamonds Grown in a Fe—Ni—C System (according to Gas Chromatography—Mass Spectrometry Data)


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Abstract

The first data of chromatography—mass spectrometry analysis of volatiles from crystals of synthetic diamonds grown in a Fe—Ni—C system at 1350–1400°С and 5.5–6.0 GPa are presented. The composition of the fluid in equilibrium with the metal-carbon melt is determined, and a comparative estimation for the compounds of different hydrocarbons and their derivatives is made. It is shown that a significant role in these processes is played by high-molecular-weight hydrocarbons; and the total share of hydrocarbons and their derivatives in the fluid compounds can exceed 86%.

About the authors

A. A. Tomilenko

Sobolev Institute of Geology and Mineralogy, Siberian Branch

Author for correspondence.
Email: tomilen@igm.nsc.ru
Russian Federation, Novosibirsk

T. A. Bul’bak

Sobolev Institute of Geology and Mineralogy, Siberian Branch

Email: tomilen@igm.nsc.ru
Russian Federation, Novosibirsk

A. I. Chepurov

Sobolev Institute of Geology and Mineralogy, Siberian Branch

Email: tomilen@igm.nsc.ru
Russian Federation, Novosibirsk

V. M. Sonin

Sobolev Institute of Geology and Mineralogy, Siberian Branch

Email: tomilen@igm.nsc.ru
Russian Federation, Novosibirsk

E. I. Zhimulev

Sobolev Institute of Geology and Mineralogy, Siberian Branch

Email: tomilen@igm.nsc.ru
Russian Federation, Novosibirsk

N. P. Pokhilenko

Sobolev Institute of Geology and Mineralogy, Siberian Branch

Email: tomilen@igm.nsc.ru
Russian Federation, Novosibirsk

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