Methylviologen-mediated electrochemical synthesis of platinum nanoparticles in solution bulk
- 作者: Yanilkin V.1, Nastapova N.1, Nasretdinova G.1, Fazleeva R.1, Fedorenko S.1, Mustafina A.1, Osin Y.2
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隶属关系:
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
- Interdisciplinary Center “Analytical Microscopy”
- 期: 卷 53, 编号 5 (2017)
- 页面: 509-521
- 栏目: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188708
- DOI: https://doi.org/10.1134/S1023193517050160
- ID: 188708
如何引用文章
详细
Platinum nanoparticles (PtNPs) are synthesized by methylviologen-mediated reduction of PtCl2 at the potentials of the MV2+/MV•+ redox couple in 40% aqueous DMF solution. In the absence of stabilizing agents and in the presence of a stabilizer in the form of spherical silica NPs or alkylamine-modified silica NPs (SiO2-NHR), a part of PtNPs (14–18%) are deposited on the electrode while the rest of particles remain in solution to form coarse aggregates which precipitate. In the latter case, PtNPs are also partly bound to form individual ultrafine NPs (3 ± 2 nm) on the SiO2-NHR surface. In the presence of polyvinylpyrrolidone (PVP), the generated PtNPs (18 ± 9 nm) neither aggregate nor deposit on the cathode but are completely stabilized in solution being encapsulated within the PVP matrix. The obtained PtNPs are characterized by the methods of dynamic light-scattering and electron microscopy.
作者简介
V. Yanilkin
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
编辑信件的主要联系方式.
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420088
N. Nastapova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420088
G. Nasretdinova
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420088
R. Fazleeva
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420088
S. Fedorenko
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420088
A. Mustafina
Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420088
Yu. Osin
Interdisciplinary Center “Analytical Microscopy”
Email: yanilkin@iopc.ru
俄罗斯联邦, Kazan, 420018