Formation of diffusion zones around growing clusters during electrocrystallization of metals


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Resumo

The problem of the radius of depleted-by-diffusion zones around the growing individual clusters during the electrocrystallization in the mode of diffusion kinetics is solved. It is shown that a decrease in the probability of nucleation in every prescribed instant of time depends on the diffusion coefficient, overpotential, and individual characteristics of deposited metal: a specific surface energy and molar volume.

Sobre autores

Yu. Gamburg

Frumkin Institute of Physical Chemistry and Electrochemistry

Autor responsável pela correspondência
Email: gamb@list.ru
Rússia, Leninskii pr. 31, Moscow, 119071

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