Polarization of the contact between fluorine-conducting solid electrolyte and metal alloys
- Autores: Turaeva M.1, Urchukova M.2, Tarasenkova I.1
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Afiliações:
- Agrophysical Institute
- NTF “Volta,”
- Edição: Volume 53, Nº 6 (2017)
- Páginas: 627-635
- Seção: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/188776
- DOI: https://doi.org/10.1134/S1023193517060167
- ID: 188776
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Resumo
The kinetics of low-sized phase formation on polarization of the interface between LaF3:Eu2+ and Pb–Sn, Sn–Bi, and Sb–Bi alloys is studied by the potentiostatic and linear voltammetry methods. The analysis of anodic transients shows that the new phase formation involving fluoride ions from the solid electrolyte proceeds by the mechanism of instantaneous two-dimensional or three-dimensional nucleation. Comparison of calculated and experimental transients describing the instantaneous nucleation with either two-dimensional growth on the I/Im vs. t/tm coordinates or three-dimensional growth on the I2/Im2 vs. t/tm coordinates shows adequate agreement between the model and the initial regions of experimental curves. The properties of phases formed depend on the alloy composition and the polarization conditions as well as on the energy of interaction between components in the alloy and in the new phase.
Sobre autores
M. Turaeva
Agrophysical Institute
Autor responsável pela correspondência
Email: margtur@mail.ru
Rússia, St. Petersburg
M. Urchukova
NTF “Volta,”
Email: margtur@mail.ru
Rússia, St. Petersburg
I. Tarasenkova
Agrophysical Institute
Email: margtur@mail.ru
Rússia, St. Petersburg