Performance of a Li-Polyimide Battery with Electrolytes of Various Types
- Авторлар: Yarmolenko O.1, Romanyuk O.1, Slesarenko A.1, Baymuratova G.1, Shuvalova N.1, Mumyatov A.1, Troshin P.1,2, Shestakov A.1,3
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Мекемелер:
- Institute of Problems of Chemical Physics
- Skolkovo Institute of Science and Technology
- Faculty of Fundamental Physicochemical Engineering
- Шығарылым: Том 55, № 4 (2019)
- Беттер: 254-264
- Бөлім: Article
- URL: https://journals.rcsi.science/1023-1935/article/view/192015
- DOI: https://doi.org/10.1134/S1023193519020174
- ID: 192015
Дәйексөз келтіру
Аннотация
—The effect of various types of electrolyte on the behavior of lithium-polyimide batteries was studied. The electrolyte systems used included the liquid 1 M LiPF6 electrolyte in ethylene carbonate/dimethyl carbonate (1: 1), plasticized polymer electrolyte based on the polyvinylidene fluoride copolymer with hexafluoropropylene, and nanocomposite electrolyte with SiO2 nanoparticles introduced in different amounts. The structure rearrangement of polyimide during lithiation—delithiation was studied by cyclic voltammetry (CV), charge—discharge cycling, and quantum—chemical modeling using four types of electrolyte. The use of the polymer and nanocomposite electrolyte was shown to increase the discharge capacity of the polyimide cathode compared to that of the cell with liquid electrolyte, but the structural degradation of the polyimide cathode cannot be avoided.
Негізгі сөздер
Авторлар туралы
O. Yarmolenko
Institute of Problems of Chemical Physics
Хат алмасуға жауапты Автор.
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
O. Romanyuk
Institute of Problems of Chemical Physics
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
A. Slesarenko
Institute of Problems of Chemical Physics
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
G. Baymuratova
Institute of Problems of Chemical Physics
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
N. Shuvalova
Institute of Problems of Chemical Physics
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
A. Mumyatov
Institute of Problems of Chemical Physics
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
P. Troshin
Institute of Problems of Chemical Physics; Skolkovo Institute of Science and Technology
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Skolkovo, Moscow, 143026
A. Shestakov
Institute of Problems of Chemical Physics; Faculty of Fundamental Physicochemical Engineering
Email: oyarm@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Moscow, 119991