Thermodynamic Study of Siver—Tin Selenides by the EMF Method with Ag4RbI5 Solid Electrolyte


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The system Ag-Sn-Se in the region of Ag2Se-SnSe-Se composition is studied by measuring EMF of cells with Ag4RbI5 solid electrolyte in the temperature interval of 300–450 K. Based on the results of EMF measurements, the temperature of Ag8SnSe6 polymorphous transition (355 K) is determined and the partial molar functions of silver in certain phase regions of this system are calculated. Standard thermodynamic functions of formation and standard entropies are estimated for ternary phases AgSnSe2, Ag0.84Sn1.16Se2, and two modifications of Ag8SnSe6 and also thermodynamic functions of Ag8SnSe6 polymorphous transition.

作者简介

I. Alverdiev

Ganja State University

Email: Babanlymb@gmail.com
阿塞拜疆, Ganja, AZ-1143

S. Imamalieva

Institute of Catalysis and Inorganic Chemistry

Email: Babanlymb@gmail.com
阿塞拜疆, Baku, AZ1143

D. Babanly

Institute of Catalysis and Inorganic Chemistry

Email: Babanlymb@gmail.com
阿塞拜疆, Baku, AZ1143

Yu. Yusibov

Ganja State University

Email: Babanlymb@gmail.com
阿塞拜疆, Ganja, AZ-1143

D. Tagiev

Institute of Catalysis and Inorganic Chemistry

Email: Babanlymb@gmail.com
阿塞拜疆, Baku, AZ1143

M. Babanly

Institute of Catalysis and Inorganic Chemistry

编辑信件的主要联系方式.
Email: Babanlymb@gmail.com
阿塞拜疆, Baku, AZ1143

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